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常规EA-IRMS硫同位素测试中, 硫化银(Ag2S)的需样量为0.2~1.0 mg, 硫酸钡(BaSO4)的需样量为0.35~1.5 mg, 较大的需样量已难以满足珍贵样品及微区样品的分析要求, 因此如何减少测试样品量已成为EA-IRMS测试分析工作中急需解决的问题。通过对EA-IRMS测试系统的研究发现, 在采用常规方法测试样品时, 由于初始He载气流速(100 mL/min)、进入分流接口时的流速(10 mL/min)与进入离子源时流速 (0.3 mL/min)的差异导致样品燃烧产生的目标气体中99.7%的气体被浪费, 样品的总体利用率仅有0.3%。因此如何减少样品在测试过程中的损耗, 提高样品的利用率, 从而减少需样量的关键在于缩小载气流速的差距。本实验在常规EA-IRMS测试技术基础上进行了关键改进,在元素分析仪和分流接口之间设计增加一个由六通阀和自动加热冷阱构成的装置, 自动加热冷阱可在Load模式时收集SO2气体, 六通阀在Load-Inject模式之间切换时可改变He载气流速, 通过与分流接口匹配的反吹He载气(10 mL/min)将冷阱中富集的SO2气体送入分流接口, 从而保证进入分流接口前样品燃烧产生的SO2气体全部收集。这一改进, 理论上可以将样品的利用率提高10倍, 该系统需硫量降至3~13 μg, 并且可以提高反应管的寿命, 降低清灰的频率, 提高工作效率。同时有效避免了拖尾的产生, 提高分析结果的精密度。本次微量样品实验获得的硫同位素数据与常规方法一致, 分析精度优于0.15‰(1SD), 测量值与真值的差异在0.4‰以内, 达到国际同类实验室先进水平。此外, 该方法可为微量有机碳、氮同位素EA-IRMS测试分析工作的开展提供参考经验。 相似文献
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江南造山带(湖南段)金矿成矿规律与资源潜力 总被引：1，自引：0，他引：1
扬子地块—华夏地块经历武陵期—雪峰期增生造山-碰撞造山形成江南造山带,构成统一的华南板块,进入板内演化阶段。本文从构造-岩浆作用-沉积建造角度,结合地质年代学、古地磁、岩相古地理分析,加里东运动、印支运动属陆内作用,造就了加里东期、印支期两次主要的金矿成矿事件。湖南雪峰山—幕阜山(俗称“金腰带”)加里东期和印支晚期金矿床分区成带产出,构成一条复合型造山型金矿带。区域性构造导矿、次级构造交汇或叠加控矿明显;矿石普遍发育条带状构造,属韧性剪切递进变形的产物。通过对区域成矿背景、金矿成矿理论,金矿床(体)地质特征,结合同位素地球化学、地质找矿成果及深部验证情况等多方面研究表明该成矿带深部找矿潜力巨大,2000 m以浅金远景资源量有望达到3000 t。 相似文献
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四川甲基卡锂矿伟晶岩转石分布区“3定2参”大比例尺填图法及其在青藏高原应用的意义 总被引：4，自引：0，他引：4
我国西部地区无论是新疆阿尔泰还是地处青藏高原的西昆仑地区或是松潘-甘孜成矿带,都是我国伟晶岩型矿床找矿远景区,但要么剥蚀严重,要么第四系覆盖,难以找到好的地质露头。本文以地处青藏高原东南缘的川西甲基卡矿田为例,通过近10年来的实践,探索出一套在第四系覆盖严重但又有伟晶岩转石分布地区的填图找矿方法--"3定2参"1∶2000伟晶岩转石填图法,即:定伟晶岩转石类型、尺度、密度,参考矿区内伟晶岩脉产状和地形条件。实践证明,该方法能够快速有效识别伟晶岩转石类型(冰碛物、坡积物和原地或半原地型),并可进一步确定第四系覆盖区内伟晶岩脉的类型、产状及规模,为钻探工程部署提供依据。2019年在甲基卡经8个钻孔验证,在日西柯第四系覆盖区内发现16条花岗伟晶岩脉,其中锂辉石伟晶岩脉10条,实现了新的找矿突破。这一方法同样在可尔因矿集区适用,并指导2019年"松潘-甘孜成锂带锂铍多金属大型资源基地综合调查评价"项目在上述两个地区实施钻探验证,初步探获新增氧化锂资源量超过15万吨,值得进一步推广应用。 相似文献
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Xiang Jie Xiao Keyan Carranza Emmanuel John M. Chen Jianping Li Shi 《Natural Resources Research》2020,29(1):395-414
Natural Resources Research - In the past few decades, a variety of data-driven predictive modeling techniques has led to a dramatic advancement in mineral prospectivity mapping (MPM). The random... 相似文献
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作为国际前寒武系碳酸盐岩研究的热点,微亮晶(臼齿)碳酸盐岩(简称MT)在前寒武纪古地理重塑、地层对比和古气候研究等方面具有重要研究意义,但对其成因机制的认识长期存在争论。华北克拉通南缘嵩山地区新元古界何家寨组发育大量MT沉积,被前人解释为地震液化的产物。文中对何家寨组MT发育层位进行了详细的形态描述、系统的微相分析和比较沉积学的研究,确定何家寨组MT沉积于碳酸盐缓坡沉积环境,发现MT具有早期成岩作用特征,其形态类型和宿主岩性、沉积环境之间存在密切关系。从多个方面对比探讨了MT微亮晶和地震“液化脉”之间的不同,明确指出,何家寨组MT的形成受到古海洋条件和沉积岩相的严格约束,具有鲜明的古环境意义,和地震没有必然的成因联系。 相似文献
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SUN Tao WANG Denghong LI Chao ZHANG Zengqi SUN Bin CHENG Wei LI Wanting ZHANG Aiping 《《地质学报》英文版》2020,94(2):561-562
The formation ages of global magmatic sulfide Ni-Cu deposits are from Archean to Mesozoic,the Neoarchean and Neoproterozoic are the two peaks.In China,the formation ages of magmatic sulfide deposits are from Proterozoic to Mesozoic,and the Neoproterozoic and late Paleozoic are the two peaks,.Compared with the global magmatic deposits,there is no case study of the Archean magmatic Ni-Cu sulfide deposits in China before.The nickel deposits formed in Neoproterozoic are located on the margin of the North China Block and Yangtze Block(e.g.Jinchuan,Dapoling),and those formed in the late Paleozoic are mainly distributed in the Central Asian Orogenic Belt(CAOB).Emeishan and Tarim Large Igneous Provinces(LIPs).such as Kalatongke,Yangliuping,and Pobei. 相似文献
7.
基于GPU的地形可视化加速算法研究 总被引：1，自引：0，他引：1
地形可视化是利用数字高程模型DEM,采用计算机图形学和图像处理技术进行三维地形模拟显示。该技术在深部矿产预测、矿产资源评价、虚拟现实、娱乐游戏、飞行模拟等诸多领域有着广泛的应用。随着数据量的增大,三维地形可视化的实时、流畅视觉效果受到当前的计算机硬件技术水平限制。针对这一问题,本文运用ROAM算法进行地形建模,利用GPU高速并行运算性能加速地形可视化建模速度,加速模型显示效果。实验对比表明:当计算量比较小时,加速效果不显著;随着计算量的增大,计算效果越来越明显;当计算量达到一定值时,加速效果达到一个稳定的加速趋势。研究结果为地形可视化及矿产资源评价等类似工作提供了原创性可视化技术支撑。 相似文献
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湖南仁里超大型钽铌矿床钽铌铍矿资源丰富,Ta2O5资源量达到了超大型规模,BeO资源量达到了大型规模。为进一步研究湖南仁里超大型钽铌矿床稀有金属的赋存特征、成矿规律及矿产资源综合利用前景,开展了地球化学分析、电子探针、包裹体、同位素测年及可选性试验等研究工作,通过系统梳理仁里超大型钽铌矿床的工作进展,进一步探讨了该矿床的下一步找矿思路。仁里钽铌矿床共(伴)生矿种多,稀有金属综合回收率及矿产资源采选综合利用率高,具有极大的开发利用价值,可作为绿色、环保、无尾矿范例进行高效勘查与开发。仁里矿区钽铌铍矿资源丰富,具有较好的找矿潜力,加大地质勘查资金投入有望取得钽铌铍锂等稀有金属找矿新进展。下一步应对矿区2、3、5、6号主矿脉深部矿体进行控制,力争取得钽铌铍矿找矿突破,同时加强对矿区西部或西南部隐伏锂辉石白云母钠长石伟晶岩的研究工作,力争取得锂辉石白云母钠长石伟晶岩型锂矿找矿突破。 相似文献
9.
The minerogenetic (or metallogenetic) series of mineral deposits (called minerogenetic series for short) is an academic idea (concept) of studying minerogenetic characteristics in mineral deposit geology. It uses the views of systematology and mobilism to study mineralizing processes and naturally occurring mineral deposit assemblages formed in various stages of geological development in specific tectonic environments. The minerogenetic series is also a natural classification of mineral deposits. There are five hierarchical orders in the classification, with the minerogenetic series as the basic order and the core. The first order includes three categories: minerogenetic series association, minerogenetic series type, and minerogenetic series group. The second is the minerogenetic series, which is decomposed into three orders, i.e. the third, fourth, and fifth orders. The third is the minerogenetic subseries, the fourth is mineral deposit models (types), and the fifth is mineral deposits. Minerogenetic series is comparable to a certain extent metallogenic systems both in the research content and in their own research content. The study of minerogenetic series has both great theoretical significance and practical value for mineral prospecting. However, the study is still in its initial stage and a further study remains to be conducted. 相似文献
10.
Post-collisional K-rich volcanic rocks (KVRs) can provide an opportunity to constrain the architecture of the lithosphere and the mechanisms of plateau uplift. However, their petrogenesis and geodynamic setting remain in dispute. Lithium concentrations and isotopic compositions of 87 potassic, ultrapotassic and Mg-rich potassic volcanic rocks (PVRs, UPVs, and MPRs, respectively) in SW Tibet, along with new Pb–Sr–Nd isotope data and whole-rock analyses, are used to constrain their mantle source and genesis. These rocks are characterized by very similar δ7Li values: PVRs vary from −4.9‰ to +3.2‰, UPVs from −3.9‰ to +1.7‰, and MPRs from −1.2‰ to +3.5‰. They can be classified into two groups: Group I (19 out of 87 samples) with heavier δ7Li values (+1.0‰ to +3.5‰) similar to those reported for mid-ocean-ridge and ocean-island basalts (MORBs and OIBs, respectively), and Group II (68 out of 87 samples) with lighter values (−4.9‰ to +1.0‰) similar to those of Indian lower crust. These variable isotopic compositions may record the isotopic signature of the early-middle Miocene subcontinental lithospheric mantle (SCLM). This paper demonstrates the existence of isotopically light mantle domains beneath the Lhasa terrane, which were ascribed to the interaction with fluids/melts derived from the subducted Indian lower crust. The modeling curves of Indian lower crust with a metasomatized mantle composition fully account for compositional variations in the PVRs, UPVs, and MPRs. They were generated by the partial melting of SCLM, which was metasomatized by fluids/melts derived from the subducted Indian lower crust (ca. 4–14%, ca. 4–10%, and ca. 6–10% for the PVRs, UPVs, and MPRs, respectively). The Li isotopic data indicate that the Indian lower crust was subducted beneath the central Lhasa subterrane, and this sheds new light on the formation of the Tibet Plateau. 相似文献